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Chem help. (1 Viewer)

jarrad

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Given: Cl2 = 58 kcal/mole ------> 2cl

1. 58 kcal/mole is the bond dissociation energy T F

2. 58 kcal/mole is an entropy term T F

3. this reactin is endothermic T F

I dont understand it! Any help woud be appreciated.
 

BlackJack

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1. T.
2. F. Not quite, at least I do not think so.
3. T.

Think of it this way. The two chlorine atoms bonded together are more happy, as they have less energy. You need to put in energy to break the bonds, forcing them apart.
This energy has to come from the outside (eg. heat). Hence, endothermic.

Entropy is another concept, it describes something else.
 

Slidey

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How does happy equate to endothermic? :p

"The two chlorine are happy, hence endothermic."
 

~*HSC 4 life*~

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'happy' meaning the two chlorine are in their lowest energy/ground states i think. The left to right reaction is endothermic because it requires an input of energy to break the bonds holding the two cholrine atoms together so that they can form the product
 

xiao1985

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agreed on black jack...

also 2 is definitely false...
enthalpy and entropy are two completely different concepts,
 

nit

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Entropy can, at a simple level, be defined as a measure of the disorder of a system - ie it relates to the random, chaotic motion of molecules. The property of entropy comes in handy when describing the 2nd and 3rd laws of thermodynamics. In any case, all that is required here is a knowledge of the units of entropy. Basically entropy is represented by S in chem literature, heat as q, temperature as T. Then dS = dq(rev)/T. You can ignore the rev (reversible), and think of a change in entropy of a substance - ie change in disorder and chaotic motion of the molecules of the substance - as governed mainly by the change in heat (which is viewed as a chaotic energy change, as opposed to the more ordered work w). so, given that heat has units Joules/mole, and temperature has units Kelvin, entropy has units joules (or calories, but more conventionally joules)/Kelvin/mole.
 

xiao1985

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lolz i'd rep u again if i can nit... =p

btw nice result u got there =)
 

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