Is this the dot point youre talking about?
"Perform first-hand investigations to observe the flame colour of Na+, K+, Ca2+, Ba2+, Sr2+ and Cu2+."
When the ions are aspirated into the flame the elctrons absorb energy and get promoted to higher energy levels. When the electrons release the energy they fall back to the ground state. The energy is released as electromagnetic radiation of specific frequencies. Each individual element has a unique emission spectrum by which it can be identified and measured (Atomic Absorption Spectroscopy).
So each of the ions above will produce their own colour when aspirated into a flame.
Na+ - Yellow
K+ - Lilac
Ca2+ - Red-orange
Ba2+ - Light Green
Sr2+ - Crimson
Cu2+ - Green/Blue-green depending on the presence of a halide anion.