Gay Lussac's Law
"the ratio of the volumes of gases involved in a reaction if measured at the same temperature and pressure, are expressed by small, whole numbers"
Avagadro's Law
"equal volumes of gases measured temperature and pressure, contain equal numbers of molecules"
eg. in the equation 2H2 + O2 --> 2H20
in 2L of H2 there must be the same number of molecules as in 2L of O2, therefore, in 2L of H2 there must be twice the number of molecules there are in 1L of O2, providing they are the same temperature and pressure.
In your example there are 13 moles of O2 and 2 moles of C4H10, so if you have 40ml of butane, you will need 13/2 x 40ml of oxygen to completely burn it (because there are 13/2 times more molecules in oxygen), which will produce 8/2 x 40ml of carbon dioxide.
I hope that helps a bit...