From these 2 graphs, pick any x co-ordinate, e.g.
Let x = 1, graphically, you can see that:
at x = 1 on y = arccos(x), y = 0
at x = 1 on y = arccos(-x), y = π
add these two y values and you get π.
Do this for any x co-ordinate in the domain and you will get π.
Algebraically:
= arccos(x) + arccos(-x)
As arccos = π - arccos(x) using this trig identity,
= arccos(x) + π - arccos(x)
= π