We can ignore 7,8,9 without loss of generality, as they do not exert any restraints on the ordered pairs. They contribute a factor of 7 X 8 X 9 possibilities to the total number of sequences possible. Without loss of generality, fix the order of the digit pairs.
The first position must contain an odd number. Let this odd number be A, and it's even counterpart be A*. Then there are five possible cases for the position of A*. In each case, the next odd number, B, will follow in either the second or third position. The third position can only occur in the case where A is immediately followed by A* . Then in each case, B* has only three possible positions. With the remaining two slots, there is only one way C and C* can be placed to complete the six-digit number. Thus, the total number of possibilities is 9 X 8 X 7 X 5 X 3 X 3! = 45360