Draw u ice table, change in h2 is 2x=0.36, so x=0.18 change in methanol is -x change in CO is +x. Final mole for H2 is 0.5+0.36, For CO it's 1+0.18 and Methanol 2.5-0.18. Divide all these by 2 because final volume is 2L to get concentration. Then just plug into the K expression.
Technically both B and D are wrong, but i think they'd accept D as more correct since it has repeated sub units, so i dunno. I didn't think it was B because it didn't have repeated sub units, which i believe is in the definition of a polymer.