ohhh right ic but how do you know the amounts of OH- and H3O are small tho?
Good question. This ion has the ability to be both a proton donor and a proton acceptor. That tells us something about how this ion is going to behave in water. If you try to lower the pH of the solution by adding more H
3O
+, it will react with them, and if you try to raise the pH of the solution by adding OH
- it will react with them too. So the pH can't move very far away from neutral which is 7 or -log[H
+], and we know that from the K
a of water. That is how we can deduce that the concentrations of H
3O
+ and OH
- must be small.