From the graph at 25deg Celsius 8mg/L is the concentration.
at 10L --> 80mg of O2 is dissolved
at 10L --> 0.08g of O2 is dissolved
n(O2) = 0.08/16+16 = 0.0025
V = moles x 24.79 (because it's at 25 degress celcius)
V = 0.0025 x 24.79 = 0.0619L = 62ml :. a