hmm never really thought about it, and can't really think of a worded explanation... but I know that for m/s^-2 and N/kg you're using the 2 known equations for acceleration (which is what gravitation is - acceleration of a mass in a field due to force)
a = change in v/ change in t
(this logically gives the rate of change of motion - velocity - for every second, giving m/s/s) ie how fast an object is speeding up per unit of time
F = ma
If you rearrange this, you get:
a = F/m
Using this equation, the units you get for the acceleration are derived from the units for the components in the equation:
ie F is measured in Newtons and mass is measured in kg
Inserting this into the equation, you get:
a = N/kg
So therefore acceleration due to the gravitational field is measured in Newtons per kg (N/kg) as well as the obvious metres per second, per second.
I guess it's a matter of using the equation F = ma and using the units of the components?
Hope that helps in some warped way, haha. Hmm don't really know of another explanation, so if someone can do this in a more comprehensive way, the floor is yours! (it'll help me too
)