1. Weigh out a certain amount of Na2CO3 (let's say 4 grams) in watchglass
2. If you're really pedantic, heat it in oven and cool it in a dessicator, and reweigh.
3. Transfer Na2CO3 into beaker, and add some deionised water to dissolve it.
4. Transfer solution into a 250mL volumetric flask
5. Add distilled water to the volumetric flask until the meniscus lies on the graduated mark.
6. Place stopper over volumetric flask and shake like hell.
To calculate the concentration of this Na2CO3 standard solution, first find the number of moles of Na2CO3.
Assuming 4 grams was weighed out. n = 4 / 106 <-- molar mass of sodium carbonate
Therefore no. of moles = 0.03773...
Concentration = 0.03773 / 0.25 = 0.15 M
0.15M standard solution of sodium carbonate was prepared.