I think it would be because the tangent of ex at x=0 is 1, whereas this is not true for any other number (the tangent of ax at x=0 is ln a]).
The y value at x=0 will be 1 for the exponential function. The tangent of x+1 is always 1, and y=1 for x=0. So, if dy/dx is lower than 1 at x=0, as x increases, y decreases at a lesser rate than x+1 and so 'sinks' beneath it. If dy/dx is greater than 1 at x=0, then as x decreases, y will decrease at a greater rate than in x+1, and again it will 'sink' beneath it.
So the tangent at x=0 must be 1, which is true only for e.