I'm not sure what conditions they give you molar volumes for - 24.79 looks like theyve given you molar volumes at 298.15K, 100kPa. In this case, 100kPa isn't strictly atmospheric pressure, but rather 101.3 is. The molar coefficient comes out to be 24.47 L/mol which gives 6.12L. It wouldn't have mattered too much given this was a multiple choice q.
Edit: the way you arrive at these coefficient values is beyond the scope of the course. But it comes from the empirically-derived equation:
PV=nRT, P=pressure, V=volume in litres, n=no. moles, R=ideal gas constant, T=Kelvin Temp. Put P in kilopascals, then R=8.314; if P is in atmospheres, then R=0.08206. Plugging in the right values gives you the values 24.79 and 24.47