Chemistry Predictions/Thoughts (1 Viewer)

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The addition of chlorine to an alkene produces a dichloroalkane.

The fact that the mass spectrum appears to show only one is misleading. The product should be 1,2-dichloropropane.

The mass spectrum of the compound can be seen at this link: https://webbook.nist.gov/cgi/cbook.cgi?ID=C78875&Mask=200#Mass-Spec

You can see that it matches the spectrum provided in the exam, but with the lowest intensity peaks missing.

Taking the 35Cl : 37Cl ratio as 3 : 1 yields the parent (molecular) ion, [C3H6Cl2]+ . at m/z = 112, 114, and 116 in a 9 : 6 : 1 ratio.
doesnt 1,2-dichloroprop-1-ene fit cause you could assume Q might have a double bond and since doesnt specify excess cl2 it could only have 1 double bond being saturated also 1,2-dichloroprop-1-ene has 32 percent carbon by mass and has molecular ion peak at 114 it also has a fragment at 15 and 62?
 

Jane Mao

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Solutions ?
Surely multiple choice at least ;)
Rather than wait for some genius person who got everything right, how bout we just compile everyone’s answers.
Here’s what I had for everything
1. D
2. C
3. B
4. D
5. D
6. C
7. A
8. B
9. C
10. A
11. C
12. B
13. A
14. D
15. B
16. B
17. A
the full paper isn’t uploaded yet so I can’t check this but I think I got all A’s for 18, 19, and 20 (I rushed multiple choice so this could be wrong)
Now if anything looks wrong just tell me and I’ll edit this
 
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jc7726

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Rather than wait for some genius person who got everything right, how bout we just compile everyone’s answers.
Here’s what I had for everything
the full paper isn’t uploaded yet so I can’t check this but I think I got all A’s for 18, 19, and 20 (I rushed multiple choice so this could be wrong)
Now if anything looks wrong just tell me and I’ll edit this
I think i got something like
1D 2C 3B 4D 5D 6C 7A 8C 9C 10A 11C 12B 13A 14(idk but i think B?) 15B 16B 17(idk but i think A) 18(A i think) 19(also A i think) 20D

not sure that these are exactly what i put for everything but i think it's decently close
 

Goldattacker40000

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Rather than wait for some genius person who got everything right, how bout we just compile everyone’s answers.
Here’s what I had for everything
1. A
2. C
3. B
4. D
5. D
6. C
7. A
8. B
9. D
10. A
11. C
12. B
13. A
14. D
15. B
16. B
17. C
the full paper isn’t uploaded yet so I can’t check this but I think I got all A’s for 18, 19, and 20 (I rushed multiple choice so this could be wrong)
Now if anything looks wrong just tell me and I’ll edit this
1. D
2. C
3. B
4. D
5. D
6. C
7. A
8. C
9. C
10. A
11. C
12. B
13. A
14. D
15. B
16. B?
17. A
I forgot what 18-20 were.
 

Jane Mao

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I think i got something like
1D 2C 3B 4D 5D 6C 7A 8C 9C 10A 11C 12B 13A 14(idk but i think B?) 15B 16B 17(idk but i think A) 18(A i think) 19(also A i think) 20D

not sure that these are exactly what i put for everything but i think it's decently close
Lol I had a typo for question 1. Please don’t pour organic stuff down the sink :D
Hmm you guys are probably right about 9 since it gets neutralised really fast.
 

lounjg

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I think i got something like
1D 2C 3B 4D 5D 6C 7A 8C 9C 10A 11C 12B 13A 14(idk but i think B?) 15B 16B 17(idk but i think A) 18(A i think) 19(also A i think) 20D

not sure that these are exactly what i put for everything but i think it's decently close
i think 14 was D, in the exam i chose C lol,i read sodium carbonate and thought it was nahco3, doing this lead me to 29.
 

Jane Mao

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How did you guys prove NH4Cl was a B-L acid? I’m trying to write up dot point solutions
 

geug

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bruh anyone remember what q19 dont remember what i put for that shit
 

jc7726

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1. D
2. C
3. B
4. D
5. D
6. C
7. A
8. C
9. C
10. A
11. C
12. B
13. A
14. D
15. B
16. B?
17. A
I forgot what 18-20 were.
i genuinely cant remember what i put for 14 so i might have had the same answer as u, possibly not tho idk
 

jc7726

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You were given a mass spec and asked which produced the peak at 43 or something
I knew it was between A or B but i didn't know which had the + on it and i didn't know if that was the charge or not 😭 so i just had the one where the thing that didnt contain the O had the + which was A i think
 

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