Ok, I done some research and here are my findings...
1. Paddle wheel showed cathode rays were particles, as it demonstrated that they had momentum
2. Magnetic fields showed they were particles, because waves don't get deflected by magnetic fields
3. Electric fields showed they were particles, because again waves don't get deflected by electric fields although Hertz initally thought cathode rays were waves because he was not able to produce a strong enough electric field to produce any observable deflection
4. Ok, the maltese cross - It showed that cathode rays travelled in straight lines, which is both a particle and wave property, but the image of the maltese cross was perfectly clear and sharp, indicating that the rays did not experience any diffraction, indicating a lack of wave property. Also, it showed that all the rays were blocked out by a thin piece of metal and most waves can travel through such barriers... electrons may also be able to, but some inevitably get deflected after hitting the nucleus. A later demonstration of the cathode rays detected little sparks in the phosphor dots at the cathode end, which showed that some of the rays were completely reflected.