I am guessing this is almost, but not quite, entirely unrelated to HSC chemistry, but I'll help where pos.
Initally;
solvent>solutes
CHCl3> I2
H2O> I-
Shakey shake shake
CHCl3> I2
H2O> I- , I3 -
I am guessing you used a starch indicator for the titration which weakly bonds...